How words are interrelated in the human mind is a scientific topic on which there is still no consensus, with different views on how word co-occurrence and semantic relatedness mediate word association. Recent research has shown that lexical associations are strongly predicted by the similarity of those words in terms of valence, arousal, and concreteness ratings. In the current study, we aimed at extending these results to more complex and realistic linguistic scenarios, since human communication is not done with word pairs, but rather through sentences. Hence, the aim of the current study was to verify whether valence, arousal, and concreteness also articulate sentence-level lexical representations. To this end, 32 native Spanish speakers were given cue words and asked to use them in sentences that would provide a meaningful context. The content words of the written sentences were then analyzed. Our results showed that the emotional dimensions (valence and arousal) and concreteness values of the cue words effectively predicted the same values of said dimensions of their sentences' words. In sum, the similarity in the emotional dimensions and concreteness are crucial mechanisms behind word association in the human mind.